Assembly of vanadium-iron-sulfur cubane clusters from mononuclear and linear trinuclear reactants |
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Biochemistry. How iron activates O2. |
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Characterization and dioxygen reactivity of a new series of coordinatively unsaturated thiolate-ligated manganese(II) complexes |
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A chloride ion contained in a cobalt 'claw': [Co3(DADIT)3]Cl(PF6)2 |
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Comparison of Structurally-Related Alkoxide, Amine, and Thiolate-Ligated M (M= Fe, Co) Complexes: the Influence of Thiolates on the Properties of Biologically Relevant Metal Complexes |
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Comparison of two MnIVMnIV-bis-μ-oxo complexes {[MnIV(N4(6-Me-DPEN))]2(μ-O)2}2+ and {[MnIV(N4(6-Me-DPPN))]2(μ-O)2}2 |
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Enhancing reactivity via structural distortion |
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The first example of a nitrile hydratase model complex that reversibly binds nitriles |
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Geometric and electronic structure of a crystallographically characterized thiolate-ligated binuclear peroxo-bridged cobalt(III) complex |
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How Do Oxidized Thiolate Ligands Affect the Electronic and Reactivity Properties of a Nitrile Hydratase Model Compound? |
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How Do Ring Size and π-Donating Thiolate Ligands Affect Redox-Active, α-Imino-N-heterocycle Ligand Activation? |
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How does cyanide inhibit superoxide reductase? Insight from synthetic FeIIIN4S model complexes. |
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How Metal Ion Lewis Acidity and Steric Properties Influence the Barrier to Dioxygen Binding, Peroxo O-O Bond Cleavage, and Reactivity |
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Iron L2,3-Edge X-ray Absorption and X-ray Magnetic Circular Dichroism Studies of Molecular Iron Complexes with Relevance to the FeMoco and FeVco Active Sites of Nitrogenase |
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Isolation and characterization of a dihydroxo-bridged iron(III,III)(μ-OH)2 diamond core derived from dioxygen |
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Ligand oxidations in high-spin nickel thiolate complexes and zinc analogues |
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Metal-Assisted Oxo Atom Addition to an Fe(III) Thiolate. |
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Metal-carbon bonds in nature. |
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A model for the interaction of alcohol with the zinc thiolate site of alcohol dehydrogenase |
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Nickel-promoted reductive carbon-sulfur bond cleavage: a model for the first step in the reaction promoted by methyl coenzyme M reductase |
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Nitrile hydration by thiolate- and alkoxide-ligated Co-NHase analogues. Isolation of Co(III)-amidate and Co(III)-iminol intermediates. |
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Periodic trends within a series of five-coordinate thiolate-ligated [MII(SMe2N4(tren))]+ (M = Mn, Fe, Co, Ni, Cu, Zn) complexes, including a rare example of a stable CuII-thiolate |
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Persulfide-bridged iron-molybdenum-sulfur clusters of biological relevance: two synthetic routes and the structures of intermediate and product clusters |
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Probing the influence of local coordination environment on the properties of Fe-type nitrile hydratase model complexes |
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Properties of square-pyramidal alkyl-thiolate Fe(III) complexes, including an analogue of the unmodified form of nitrile hydratase |
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Role of protons in superoxide reduction by a superoxide reductase analogue |
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S K-edge X-ray absorption spectroscopy and density functional theory studies of high and low spin {FeNO}7 thiolate complexes: exchange stabilization of electron delocalization in {FeNO}7 and {FeO2}8. |
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Steric and electronic control over the reactivity of a thiolate-ligated Fe(II) complex with dioxygen and superoxide: reversible mu-oxo dimer formation. |
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Structural and spectroscopic characterization of metastable thiolate-ligated manganese(III)-alkylperoxo species |
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Structural chemistry of vanadium-iron-sulfur clusters containing the cubane-type [VFe3S4]2+ core |
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Structural Comparison of Five-Coordinate Thiolate-Ligated MII= FeII, CoII, NiII, and ZnIIIons Wrapped in a Chiral Helical Ligand |
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Sulfur K-edge XAS and DFT calculations on nitrile hydratase: geometric and electronic structure of the non-heme iron active site |
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Synthesis and reactivity of the first structurally characterized heterobimetallic complex containing an unsupported bridging sulfur atom |
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Synthesis and structural characterization of a series of Mn(III)OR complexes, including a water-soluble Mn(III)OH that promotes aerobic hydrogen-atom transfer |
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Synthetic models for the cysteinate-ligated non-heme iron enzyme superoxide reductase: observation and structural characterization by XAS of an Fe(III)-OOH intermediate |
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Tuning the Relative Stability and Reactivity of Manganese Dioxygen and Peroxo Intermediates via Systematic Ligand Modification |
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Understanding the Mechanism of Superoxide Reductase Promoted Reduction of Superoxide |
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Water-soluble Fe(II)-H2O complex with a weak O-H bond transfers a hydrogen atom via an observable monomeric Fe(III)-OH. |
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Why is there an "inert" metal center in the active site of nitrile hydratase? Reactivity and ligand dissociation from a five-coordinate Co(III) nitrile hydratase model |
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X-ray Absorption and Emission Study of Dioxygen Activation by a Small-Molecule Manganese Complex |
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X-ray Spectroscopy of Nitric Oxide Binding to Iron in Inactive Nitrile Hydratase and a Synthetic Model Compound |
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